I can't think of a specific one off the top of my head but I like nature documentaries and paranormal ones. Especially paranormal ones. I also saw one on Hurricane Katrina that was decently interesting.
There are quite a few. I have been watching a lot of them. Especially as a kid. You can say that certain Documentaries could even be considered my childhood. Not sure about my most Favorite but this is certainly one of them. It was around the time where I realized how much relatable a Dinosaur can really be. The Allosaurus has allways been one of my favorite ones as well. Pre-history in general was all the rage for me. It still is. Many documentaries like these provided to me an even bigger inspiration towards wanting to become a Paleontologist !!!!
I don`t know about one best, but I have seen quite a lot just by living in youtube. There was a very interesting one about split personality disorder and another one about Chernobyl that I remember in particular.