your top 5........

Captains:

1. Mayuri Kurotsuchi

2. Kuchiki Byakuya

3. Kenpachi Zaraki

4. Genryūsai Yamamoto

5. Shunsui Kyōraku

Espada:

1. Baraggan Louisenbairn

2. Grimmjow Jaegerjaquez

3. Ulquiorra Cifer

4. Szayel Aporro Granz

5. Tie between Nnoitra Gilga and Zommari Rureaux

Zanpakuto:

1. Ashisogi Jizō (Mayuri)

2. Hyōrinmaru (Hitsugaya) [that might surprise some people]

3. Hōzukimaru (Ikkaku)

4. Senbonzakura (Byakuya)

5. Kazeshini (Hisagi)

Captains:

1. Shunsui Kyoraku

2. Kuchiki Byakuya

3. Jushiro Ukitake

4. Zaraki Kenpachi

5. Aizen Sosuke (Not sure what category he fits under, but I have to say he's one of my favourites)

Espada:

1. Coyote Starrk

2. Ulquiorra Cifer

3. Nnoitra Jiruga

4. Grimmjow Jaggerjack

5. Barragan

Zanpakuto:

1. Sogyo no Katawari

2. Kyoka Suigetsu

3. Raiko

4. Senbonzakura

5. Ryuujin Jakka

Mine:

1. Hitsugaya Toshiro
2. Kuchiki Byakuya
3. Ichimaru Gin
4. Soi Fon
5. Zaraki Kenpachi

Espada

1.Neliel Tu Odeschvank
2.Grimmjow
3.Uloquirra
{ I like only 3 of them )

Zanpaktou

1. Hyourinmaru
2. Sode no Shirayuki
3. Senbousakura
4. Zangetsu
5. Sōgyo no Kotowari

1.toushiro hitsugaya
2.aizen
3.kichiki
4/sajin
5.tenkin

Soi Fon
Ukitake
Kyoraku
Byakuya
Mayuri

Ulquiorra
Grimmjow
Nel
Hallibel
Stark

Suzemebachi
SogyonoKotowari
Katen Kyokatsu
Senvonzakura
Haineko

Captains:

1.Kuchiki Byakuya

2.Ichimaru Gin

3.Zaraki Kenpachi

4.Aizen Sousuke

5.Kurotsuchi mayuri

Espadas:

1.Szayel Aporro Granz

2.Ulquiorra Schiffer

3.Grimmjow Jeagerjaques

4.Coyote Stark

5.Nnoitra Jiruga

Zampakuto:

1.Tensa Zangetsu

2.Sode no Shirayuki

3.Senbonzakura

4.Katen Kyokotsu

5.Zabimaru

captain:
Tōshirō Hitsugaya
Shunsui Kyōraku
Jūshirō Ukitake
Zaraki Kenpachi
Byakuya Kuchiki
Espada:
Nel #3 (former)
Grimmjow #6
Ulquiorra #4
Szayel Aporro #8
Tia Harribel #3
Zanpaku-to
hyourinmaru
Gamuza
Zabimaru
Senbonzakura

CAPTAIN
1.gin ichimaru
2.toshiro hitsugaya
3.sajin komamura
4.kenpachi zaraki
5.soifon

ESPADA
1.grimmjow
2.ulquiora
3.aizen
4.halibell
5.noitora/szayelaporro grantz
ZANPAKU-TO
1.zangetsu (I <3 THIS ZANPAKU-TO)
2.Sode no Shirayuki
3.hiyorimaru
4.Hoozukimaru
5.Shinsou

^_^ BLEACH LOVER LOL ichigo rulz :P

I change captains to soul reapers so these are my Favorites

Soul Reapers:
1)Rangiku Matsumoto
2)Ichigo Kurosaki
3)Yoruichi
4)Kenpachi Zaraki
5)Toshiro Hitsuguya

Espadas:
1)Neliel Tu Oderschvank
2)Tia Halibel
3)Grimmjow Jeagerjaques
4)Ulquiorra Cifer
5)Starkk

Zanpaku-to:
1)Haineko
2)Zangetzu
3)Sode no Shirayuki
4)Hyorinmaru
5)Senbonzakura

Captains:
1. Byakuya
2. Toshiro
3. Mayuri
4. Kyoraku
5. Zaraki

Espada:
1. Grimmjow
2. Ulquiorra
3. Aizen
4. Gin
5. Wonderweiss

Zanpakuto:
1. Hyorinmaru
2. Senbonzakura
3. Waibisuke
4. zabimaru
5. Zangetsu