1.Takumi usui and Misaki ayuzawa (Kaichou wa maid sama !)
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Others :
2. Sakura and Syaoran (Card Captor Sakura...the original Japanese anime, not the crappy English edited version)
Supplementary AMVs:
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Added:Below is the best Sakura x Syaoran AMV ever!!
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3. Nanoha and Fate (Magical Girl Lyrical Nanoha)
Supplementary AMVs:
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4. Naruto and Hinata (Naruto)
Supplementary music slideshow:
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AMV:
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5. Tenma and Harima Kenji (School Rumble)- The king and queen of baka!!